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RE: [Irradiation of foods]
Keith and Chris:
One of my concerns is the possible formation of trans-fatty acids, which are considered to be a significant contributor to heart disease. I personally do not look forward to the widespread use of food irradiation.
Marty Jamieson
-----Original Message Starts Here-----
From: Keith.Millington@csiro.au
Sent: Thu, 21 Nov 2002 15:55:17 +1100
To: chofmeyr@nnr.co.za, radsafe@list.vanderbilt.edu
Subject: Irradiation of foods
Hi Chris,
One of my current interests is in free radical oxidation of proteins. If dry
proteins, for example the fibrous proteins wool and silk, (and also certain
amino acids) are mildly irradiated with gamma or UV radiation you can
easily detect free radicals using ESR (electron spin resonance)
spectroscopy. It is interesting to note that "dry " wool is hydrophilic and
contains about 15% w/w adsorbed water, which varies depending on relative
humidity.
In the presence of oxygen these radicals very gradually decay (if left for
more than 24 hours or so) and form oxidised products. In a nitrogen
atmosphere the radicals persist indefinitely (if the irradiated samples are
kept in the dark). They will later decay if exposed to atmospheric oxygen.
My naive knowledge of food oxidation processes suggests that oxidation is
usually associated with spoilage, particularly for fresh foods. Clearly
thermal oxidation occurs during cooking, although in my experience there are
usually different mechanisms and products involved in thermal, photo and
radiolytic oxidation processes.
One of the other factors involved in treating proteins with
gamma-irradiation is they quite often undergo serious colour changes.
My question is, has much research been reported on various different
foodstuffs to look at the nature of the oxidation products and colour
changes that occur by using gamma irradiation ? It seems to me that may be
some interesting R&D to do in this field. To my knowledge, the only
foodstuffs imported into Australia for human consumption that are gamma
irradiated are certain spices and herbs, and I am aware of some reported
work on these.
Best regards, Keith
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Marty Jamieson
martyj@swiftdesk.com
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