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Th-232/Ra-228
I have found that thorium mill tailings of an intermediate age 20-40 years
have a higher concentration of Th-228 than Th-232. My supposition is that
removal of the Th-232 concentrated Ra-228 in the spoils above the Th-232
concentration. As the Ra-228 in the spoils decayed the Th-228 would build
up to an equilibrium that would be above the Th-232 concentration.
Fresh thorium mill tailings would not have this effect as the Ra-228 would
not have had a chance to ingrow to the Th-228 and the Th-228 would decay
away until supported by the Ra-228 present. Much older tailings would have
the Th-228 close to equilibrium with the Th-232 as the Ra-228 that had been
concentrated had dropped back to the equilibrium value supported by the
Th-232 and thus the Th-228 value would decay to the supported equilibrium
level.
Erik C. Nielsen
Senior Radiochemist
Antech Ltd Waltz Mill Laboratory
P.O. Box 158, Bldg G, M/S 62
Madison, PA 15663
mailto:enielsen@antechltd.net
(V) 724-722-5214
(F) 724-722-5208
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