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RE: Detectors and humidity
Actually, Rick has the correct analogy of water molecules displacing air
molecules. From the ideal gas law ( PV=nRT ), it's clear that for a
given pressure, volume, and temperature, the number of molecules is
constant. So if water vapor has been added, an equal number of
molecules of air were displaced. Then it's just a matter of molecular
weights: H2O = 18, N2 = 28, O2 = 32 (dry air average about 28.8). So,
1% (by volume) of water vapor added to dry air decreases the average
molecular weight by about 0.1, or about 0.3%.
Rod
-----Original Message-----
From: John_Sukosky@DOM.COM [mailto:John_Sukosky@DOM.COM]
Sent: Tuesday, June 01, 2004 11:20 AM
To: Rick Orthen
Cc: radsafe@list.vanderbilt.edu
Subject: RE: Detectors and humidity
Rick,
The problem is what definition of air we use, dry air or air with water
vapor. If you look at it in a practical way, since water vapor is part
of air, then a cubic centimeter of air containing water vapor is denser
than a cubic centimeter of dry air (since water is denser than air). In
terms of alpha efficiency, it seems intuitive (at least to me) that
alphas would have less efficiency (and lower count rates) in air
containing water vapor than dry air. Am I misguided on this?
Here's the definition of air from free-definition.com:
Air is a name for the mixture of gases present in the Earth's
atmosphere.
Dry air is roughly 79% nitrogen, 20% oxygen, and 1% argon. Air may
contain 0-7 % water vapour (the 79%, 20% and 1% become accordingly a
little less), and less than 1% carbon dioxide.
John M. Sukosky, CHP
Dominion
Surry Power Station
(757)-365-2594 (Tieline: 8-798-2594)
"Rick Orthen"
<rorthen@cecinc.c To:
<John_Sukosky@DOM.COM>
om> cc:
Subject: RE: Detectors
and humidity
06/01/04 09:50 AM
Maybe I'm not seeing the forest for the trees, but I think it is
intuitively clear why air density decreases with increasing humidity.
As humidity increases, each cubic centimeter of air contains a larger
proportion of water molecules, effectively displacing the amount of air
in that cc cube. With less air molecules in the cube, the air density
has to go down.
Rick
Richard F. Orthen, CHMM
Senior Project Manager
Civil & Environmental Consultants, Inc.
Four Triangle Lane, Suite 200
Export, PA 15632-9255
724/327-5200, ext. 231
www.cecinc.com
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